Atkins' Physical Chemistry: Molecular Thermodynamics and Kinetics is designed for use on the second semester of a quantum-first physical chemistry course. Based on the hugely popular Atkins' Physical Chemistry, this volume approaches molecular thermodynamics with the assumption that students will have studied quantum mechanics in their first semester. The exceptional quality of previous editions has been built upon to make this new edition of Atkins' Physical Chemistry even more closely suited to the needs of both lecturers and students. Re-organised into discrete 'topics', the text is more flexible to teach from and more readable for students. Now in its eleventh edition, the text has been enhanced with additional learning features and maths support to demonstrate the absolute centrality of mathematics to physical chemistry. Increasing the digestibility of the text in this new approach, the reader is brought to a question, then the math is used to show how it can be answered and progress made. The expanded and redistributed maths support also includes new 'Chemist's toolkits' which provide students with succinct reminders of mathematical concepts and techniques right where they need them. Checklists of key concepts at the end of each topic add to the extensive learning support provided throughout the book, to reinforce the main take-home messages in each section. The coupling of the broad coverage of the subject with a structure and use of pedagogy that is even more innovative will ensure Atkins' Physical Chemistry remains the textbook of choice for studying physical chemistry.
(5A.7) As established in Topic 3E, under the same conditions dG = dw Therefore, at constant temperature and pressure, add, max" dwana, uadna + Hodne + .
(i) Li2 electron has 1+1=2 valence electrons configuration is 1σ2g. (VE) overall, therefore the ground-state Te bond order is defined in [C.–] as b = 12(N − N∗), therefore b = 12(2−0) = 1. (ii) Be2: 2+2 = 4 VE; 1σ2g 1σ∗2u; ...
Physical Chemistry
... nHI I 0.200 n I 0.900 Chan ge/mol —z —z +2z Equilibrium amount/moi nH2 — z n12 — z nHI + 22 n I 0.900 Mole fraction (nH2 — z)/n (nIZ — z)/n (nHI + 2z)/n 1 _ (PHI/PIT)2 _ I T113969“ 83595, P1 I x117] (PHZ/P )(PIZIP ) (761102 _ ("111+ ...
This revision of the introductory textbook of physical chemistry has been designed to broaden its appeal, particularly to students with an interest in biological applications.
Solutions Manual for Quanta, Matter and Change
Peter Atkins and Julio de Paula offer a fully integrated approach to the study of physical chemistry and biology.
12.27 The Morse potential energy curve reproduces the general shape ofa molecular potential energy curve. The corresponding Schrödinger equation can be solved, and the values ofthe energies obtained. The number ofbound levels is finite.
Physical Chemistry
(VE) overall, therefore the ground-state Te bond order is defined in [C.–(II)] as b = 12(N − N∗), therefore b = 12(2−0) = 1. (ii) Be2: 2+2=4 VE; 1σ2g 1σ∗2u; b = 12(2−2) = 0. (iii) C2: 4 + 4 = 8 VE; 1σ2g 1σ∗2u 1π4u; ...