Since its introduction into the armoury of the analytical chemist approximately two decades ago the technique of gas chroma tography has found very extensive applications in the analysis of most types of organic compounds. One of the few remaining limitations of the technique when applied to such compounds, namely the analysis of very highly boiling and or thermally unstable substances, has been overcome in many instances by the introduction of techniques such as silation for the conversion of sample components to lower boiling or more stable substances which can be gas chromatographed at reasonably low temperatures. All of this has been extensively dealt with in many books published during recent years dealing with the theory and practice of applying gas chromatography to the analysis and preparative separation of organic compounds. In parallel with these developments there has occurred, particu larly over the past decade, a growing interest in the application of gas chromatography to the analysis of organometallic compounds. Indeed, for many types of organometallic compounds, gas chromatography is the analytical method of choice particularly, as so often happens, when the sample is a mixture. To the author's knowledge no complete review exists of the published work in this very interesting new field; a situation it is hoped the present volume will rectify.
Chemical Analysis of Organometallic Compounds
Concerned with the use of gas chromatography to solve biological and biochemical problems. Provides thorough coverage of the methods involved--basic principles and equipment, multidimensional techniques, detectors and derivatization techniques. Several...
This book examines the occurrence, toxicity, analysis and typical concentrations of organometallic compounds in various environmental samples.
Chemical Analysis of Organometallic Compounds: Elements of Groups I-III
The tailored operation condition of a gas chromatograph fits again nicely with the AAS atomizer since the analytes are ... Since its introduction, GC-AAS has been extensively applied to speciation of organometallic compounds such as Sn, ...
This new Fourth Edition incorporates the most recent developments in the field, including entirely new chapters on gas chromatography/mass spectrometry (GC/MS); optimization of separations and computer assistance; high speed or fast gas ...
It should be noted that the field of application of GC in the analytical chemistry of complex organometallic catalysts can be greatly extended. Examples of the utilization of GC for the investigation of complexing, the structure of ...
M.G. Voronkov, V. P. Mileshkevich, Yu. A. Yuzhelerskii, Russ. Chem. Rev. (Engl. Transl.), 45 (1976) 1167 (Organosiloxane complexes). E.Ya. Lukevits, L. Liberts, M.G. Voronkov, Russ. Chem. Rev. (Engl. Transl.) ...
In recent years a great deal of interest has been expressed in the use of organometallic compounds as reagents in reaction GC. Sakharov et al. [168] proposed the use of organoalkylaluminium compounds to determine oxygen in a mixture of ...
Up to 30 fractions can be monitored subsequently by laser mass spectrometry in this mechanized off-line combination. 5 Inorganic and Organometallic Compounds Independently, chromatography and mass spectrometry are making inroads into ...