In the phase transitions among the solid, liquid, and gaseous forms of water, we see a profound demonstration of how properties at the molecular scale dictate the behavior of the bulk material. As ice is heated beyond its melting point, new avenues for molecular motion become open to the energy being added. Upon entering the gas phase, the water molecules can explore new territory, unavailable to the liquid or solid. These transformations can be seen as a shifting balance between the forces that bind the molecules and the thermal energy that excites these motions--a window through thermodynamics on the intricate mechanisms that drive chemistry.
Hard, soft, and borderline ligands are listed in Table I. From a survey of the affinities of metals for ligands, Pearson has set forth the general principle that "... hard acids prefer to associate with TABLE I Classification of Lewis ...
... SZASZ L USNYNV F EN T 80 JCP 73 6263 PUJOL L NININI F EN T 80 JFII 4 391 STEINER E UKENEX F Cl AA EN T 80 ZFKH 54 1660 ANIKIN N A SUROMZ At At EN R 61 ADND 26 199 MCLEAN A D USCAS. F EN T 61 IJOC 19 693 POIRIER R FR75PM F ClBr AA EN ...
55 ; ( c ) A. McAuley and J. Hill , Quart . Rev. ( London ) , 23 , 18 ( 1969 ) ; ( d ) D. J. Hewkin and R. H. Prince , Coord . Chem . Rev. , 5 , 45 ( 1970 ) . ( e ) D. N. Hague , Chem . Soc . Spec . Period , Rep . , No.
Charles Bernstein, Richard Barry Bernstein Oxford University Press ... Richard B. Bernstein Oxford , June 1980 Note added in proof The present manuscript has been updated somewhat from the ' lecture notes ' of June , 1980 , but there is ...
Modelling and Simulation of Chemical Reactions: A Mechanistic Point of View
53. A. B. Callear and P. M. Wood , Trans . Faraday Soc . , 67 , 272 , 598 ( 1971 ) . 54. R. G. W. Norrish and G. Porter , Disc . Faraday Soc . , 17 , 40 ( 1954 ) . 55. K. C. Herr and G. C. Pimentel , Appl . Opt . , 4 , 25 ( 1965 ) . 56.
Offering a thorough explanation of electrode kinetics, this textbook emphasizes physical phenomena - rather than mathematical formalism - and elucidates the underlying principles of the different experimental techniques.
physical sciences data 31 Other titles in this series : 1 J . Wisniak and A . Tamir , Mixing and Excess Thermodynamic Properties 2 J . R . Green and D . Margerison , Statistical Treatment of Experimental Data 3 K . Kojima and K ...
Basic Reaction Kinetics and Mechanisms
In this new edition of Fundamentals of Enzyme Kinetics all of the text has been thoroughly revised to explain concepts even more clearly, some of the material is reorganized into a more logical sequence, and there are many additions ...