Higher Excited States of Polyatomic Molecules, Volume II focuses on a higher level of activity in vacuum ultraviolet spectroscopy. This book explores the Rydberg states in atoms and molecules. Comprised of five chapters, this volume starts with an overview of the two-center unsaturated molecules that usually display sharp Rydberg transitions originating with the pi electrons. This book then discusses the unsaturated double bond that adds another dimension to the spectrum. Other chapters explore the optical spectrum of the amide group, which is the basic chromophoric unit in polypeptides. This text further discusses the all-electron calculations of the electronic structure of the amide group that is performed in Gaussian orbital basis sets. This book considers as well the prominent characteristic of Rydberg excitations in benzene. The final chapter deals with the biological molecules that are polyfunctional in general. Analytical chemists, photochemists, molecular spectroscopists, and researchers will find this book extremely useful.
For a long time, the Kasha rule (Kasha, 1950), regarding the absence of fluorescence from higher excited states of polyatomic molecules, was considered as absolutely valid with the only exception of azulene (Beer and Longuet-Higgins, ...
Concluding Remarks In conclusion, we now begin to understand the lowest excited singlet and triplet states of olefinic and polyenic systems. As discussed above, a large diversity of ... Higher excited states of polyatomic molecules.
Low and High Rydberg States C. Sándorfy ... They fly to the detector as neutral Rydberg excited hydrogen atoms and are then ionized by the field of the detector. ... (4) ROBIN, M. B. (1974) Higher Excited States of Polyatomic Molecules.
Frontiers and Advances in Molecular Spectroscopy once again brings together the most eminent scientists from around the world to describe their work at the cutting-edge of molecular spectroscopy.
15. M. B. Robin , Higher Excited States of Polyatomic Molecules , Vol . 3 , ( Academic Press , New York , 1985 ) . 16. W. T. Borden , Modern Molecular Orbital Theory for Organic Chemists , ( Prentice Hall , Englewood Cliffs , New Jersey ...
A. Amirav, U. Even, and J. Jortner, Excited-state dynamics of the isolated ultracold ovaleneu molecule, J. Chem. ... Luminescence from higher excited states and vibrational relaxation of polyatomic molecules in solutions, Opt. Spectrosc ...
The application of two - color fluorescence excitation spectroscopy to the study of high excited states was also made ... the fluorescence originating from high excited states is difficult to apply to large polyatomic molecules in which ...
Contents:Two-Color Double Resonance Spectroscopy For the Study of High Excited States of Molecules (M Ito & M Fujii)Resonantly Enhanced Multiphoton Ionization — Photoelectron Spectroscopy as a Probe of Molecular Photophysics and ...
Figure 1.3 Simple model of the process of photodissociation of a polyatomic molecule by an intense IR field: stage ... stage II—high excitation (vibrational heating) of molecules upon transitions between highly excited states; ...
n 1,1-diphenylethylene 9.0 60 cis-1,2-diethoxyethylene 0.36 13o 41o 2.3k,p ethyl vinyl ether 0.014 0.20 k,m ... 4.0ee 28gg 0.50c triphenylamine 6.6 7.6hh 0.31c N,N-diphenylamine 13 130 c Aromatics ii 17 benzene 0.028 jj 0.0001jj toluene ...