Traditionally, the teaching of phase equilibria emphasizes the relationships between the thermodynamic variables of each phase in equilibrium rather than its engineering applications. This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs. Phase Equilibrium Engineering presents a systematic study and application of phase equilibrium tools to the development of chemical processes. The thermodynamic modeling of mixtures for process development, synthesis, simulation, design and optimization is analyzed. The relation between the mixture molecular properties, the selection of the thermodynamic model and the process technology that could be applied are discussed. A classification of mixtures, separation process, thermodynamic models and technologies is presented to guide the engineer in the world of separation processes. The phase condition required for a given reacting system is studied at subcritical and supercritical conditions. The four cardinal points of phase equilibrium engineering are: the chemical plant or process, the laboratory, the modeling of phase equilibria and the simulator. The harmonization of all these components to obtain a better design or operation is the ultimate goal of phase equilibrium engineering. Methodologies are discussed using relevant industrial examples The molecular nature and composition of the process mixture is given a key role in process decisions Phase equilibrium diagrams are used as a drawing board for process implementation
This book changes the focus from the use of thermodynamics relationships to compute phase equilibria to the design and control of the phase conditions that a process needs.
Efforts have been made throughout the book to provide guidance to adequate theory and practice. The book begins with a long chapter on equations of state, since it is intimately bound up with the development of thermodynamics.
Highpressure phase behavior in mixtures can be quite complex in comparison to typical vapor–liquid equilibrium at low pressures. This can make some correct calculation results, obtained with the help of thermodynamic models, ...
This book is intended primarily for graduate chemical engineers but should also be of interest to those graduates in physics or chemistry who need to use phase equilibrium data.
This new book provides, for the first time, a thorough survey of the techniques and equipment for both high- and low-pressure phase equilibrium measurement and addresses the equally challenging task of accurately modeling or predicting the ...
This book concentrates on the topic of physical and chemical equilibrium.
This book is expected to be a Bible for MSEs.
This book combines theory and application of phase equilibria data of systems containing food compounds to help food engineers and researchers to solve complex problems found in food processing.
Computational tools allow material scientists to model and analyze increasingly complicated systems to appreciate material behavior.
Fluid Mechanics for Chemical Engineers, third edition retains the characteristics that made this introductory text a success in prior editions.