The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.
Hypercarbon Chemistry
take some satisfaction that I was correct and that, indeed, hypercarbon chemistry has a significant place on the wide palette of chemistry. Carbon can extend its bonding from Kekul ́e's tetravalent limit to five-, and even higher bonded ...
Much new chemistry rapidly evolved and allowed the recognition of the broad scope and significance of hypercoordinated carbon compounds ( in short hypercarbon ) chemistry.46 THE GENERAL CONCEPT OF CARBOCATIONS Based on the study of ...
For four decades, Petroleum Refining has guided thousands of readers toward a reliable understanding of the field, and through the years has become the standard text in many schools and universities around the world offering petroleum ...
H, H. Protonated ester Ji,a, Hz J.3, Hz Hz H. Ht Hs Hı – 13.50 (2)” leg" 3.6 –4, 73 (2) —9.33 `SOCH, – 12.77 (2) 0.9 (2 × 4) 2 |4,0 — 13.53 (2) H 3.5 #co – 13.30 (2) —5.57 (cm) —9.20 (2) —1.73 (2 x 3) >S 3.5 OCH2CH3 - 2 * – 12.67 (2) 14 ...
582 G. Wilke, H. Müller, Justus Liebigs Ann. Chem., 618, 267 (1958); 629, 222 (1960). 583 J.J. Eisch, W.C. Kaska, J. Am. Chem. Soc., 88, 2213 (1966). 584 G. Zweifel, R.B. Steele, J. Am. Chem. Soc., 89,5085 (1967).
This book covers both the preparative methodologies and chemical properties of partially and highly fluorinated organic systems.
... C.D. 16-1290 Maye, J.P. 15-719 Mayer, A. 19-2614 Mayer, C. 18-940 Mayer, E. 11-409 Mayer, J. 2-322, 9-115 Mayer, ... 19-1085 McDonagh, P.M. 4-412 McDonald, A.R. 10-425, 10-893 McDonald, C.E. 6-161 McDonald, D.Q. 15-102 McDonald, ...
(b) G. A. Olah; T. Mathew; E. R. Marinez; P. M. Esteves; M. Etzkorn; G. Rasul; G. K. S. Prakash; J. Am. Chem. Soc. ... (55) Z. Tang; F. Jiang; L.-T. Yu, X. Cui; X. Cui; L.-Z. Gong; A.-Q. Mi; Y.-Z. Jiang; Y.-D. Wu J. Am. Chem. Soc.
This widely acclaimed serial contains authoritative reviews that address all aspects of organometallic chemistry, a field which has expanded enormously since the publication of Volume 1 in 1964.